Poly[diaquabis[μ2-2,4-(dichlorophenoxy)acetato-κ2 O:O′]iron(II)]
نویسندگان
چکیده
In the title compound, [Fe(C(8)H(5)Cl(2)O(3))(2)(H(2)O)(2)](n), the Fe(II) atom is located on an inversion center. It is coordinated by four O atoms from four 2,4-dichloro-phenoxy-acetate ligands and two water mol-ecules, displaying a distorted octa-hedral geometry. The carboxyl-ate groups of the 2,4-dichloro-phenoxy-acetate ligands link the Fe atoms, forming a polymeric layered network in the bc plane. Intra-layer O-H⋯O hydrogen bonds enhance the stability of the two-dimensional network.
منابع مشابه
catena-Poly[[tetrakis(μ2-acetato-κ2 O:O′)dicopper(II)(Cu—Cu)]-μ2-acetato-κ2 O:O′-[bis[μ2-3-(dimethylamino)propan-1-olato]-κ2 N,O:O;κ2 O:N,O-bis[(tetrahydrofuran-κO)copper(II)]]-μ2-acetato-κ2 O:O′]
The title complex, [Cu(4)(C(5)H(12)NO)(2)(C(2)H(3)O(2))(6)(C(4)H(8)O)(2)](n), consists of dinuclear [Cu(2)(C(5)H(12)NO)(2)(THF)(2)] (THF is tetra-hydro-furan) and [Cu(2)(CH(3)COO)(4)] units linked through acetate ions, generating parallel one-dimensional polymeric chains propagating in the [10] direction. In the first dinuclear unit, Cu(II) ions related by inversion symmetry are bridged by two ...
متن کاملPoly[bis(μ4-acetato-κ4 O:O:O′:O′)bis(μ3-acetato-κ3 O:O:O)(μ2-acetato-κ2 O:O′)(μ2-acetic acid-κ2 O:O′)di-μ-aquacopper(II)trisodium]
In the title compound, [CuNa(3)(CH(3)CO(2))(5)(CH(3)COOH)(H(2)O)(2)](n), the Cu(II) atom lies on an inversion center and is coordinated by four O atoms from four acetate ligands, leading to a square-planar geometry. One Na(I) atom, lying on an inversion center, is coordinated by four O atoms from four acetate ligands and two bridging water mol-ecules in a distorted octa-hedral geometry. The oth...
متن کاملPoly[bis(μ3-acetato-κ4 O,O′:O:O′)bis(μ2-acetato-κ3 O,O′:O)(μ2-2,5-dimethylbenzene-1,4-diol-κ2 O:O′)dilead(II)]
The title compound, [Pb(2)(C(2)H(3)O(2))(4)(C(8)H(10)O(2))](n), has a polymeric structure, with acetatolead(II) chains and 2,5-dimethyl-benzene-1,4-diol mol-ecules forming bridges between two Pb(II) ions from neighbouring chains. Each Pb(II) centre is surrounded by eight O atoms; four belong to bidentate acetate ions, three to neighbouring bridging acetate groups and one to the 2,5-dimethyl-ben...
متن کاملCrystal structures of three lead(II) acetate-bridged diaminobenzene coordination polymers
Poly[tris-(acetato-κ(2) O,O')(μ2-acetato-κ(3) O,O':O)tetra-kis-(μ3-acetato-κ(4) O,O':O:O')bis-(benzene-1,2-di-amine-κN)tetra-lead(II)], [Pb4(CH3COO)8(C6H8N2)2] n , (I), poly[(acetato-κ(2) O,O')(μ3-acetato-κ(4) O,O':O:O')(4-chloro-benzene-1,2-diamine-κN)lead(II)], [Pb(CH3COO)2(C6H7ClN2)] n , (II), and poly[(κ(2) O,O')(μ3-acetato-κ(4) O,O':O:O')(3,4-di-amino-benzo-nitrile-κN)lead(II)], [Pb(CH3COO...
متن کاملPoly[μ2-benzene-1,3-dicarboxylato-κ2 O:O′-μ2-1,3-di-4-pyridylpropane-κ2 N:N′-zinc(II)]
The title compound, [Zn(C(8)H(4)O(4))(C(13)H(14)N(2))](n), was obtained by the hydro-thermal reaction of Zn(OAc)(2)·H(2)O with 1,3-di-4-pyridylpropane (bpp) and isophthalic acid (H(2)ip). The Zn(II) ion is coordinated by two bpp and two ip ligands in a distorted tetra-hedral environment. Each ligand coordinates in a bridging mode to connect Zn(II) ions into a three-dimensional diamondoid-type s...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره 64 شماره
صفحات -
تاریخ انتشار 2008